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    PIC: Gossip Girl's Leighton Meester, Penn Badgley Kiss on Set!

    PIC: Gossip Girl's Leighton Meester, Penn Badgley Kiss on Set!

    Guess hell has frozen over.

    Blair Waldorf (Leighton Meester) and Dan Humphrey (Penn Badgley) struck up an unexpectedly flirty friendship on season four of Gossip Girl -- but Brooklynite Humphrey's growing romantic feelings for Blair were thwarted by both her undying love for Chuck Bass (Ed Westwick) and an engagement to Monaco royal Prince Louis (Hugo Becker).

    PHOTOS: Leighton's worst looks ever

    But, shooting scenes for the CW hit in NYC on Monday, Meester (in a dramatic pink gown) and Humphrey were photographed in a passionate kiss.

    PHOTOS: Biggest OMG moments on Gossip Girl

    On the landmark 100th episode which aired Jan. 30, Dan provided the getaway car for Blair after her disastrous wedding to Prince Louis (who angrily vowed they'd have a loveless, obligatory marriage after she was discovered speaking romantically with Chuck).

    No word yet on whether the lip-lock -- the unlikely pair have yet to kiss -- was perhaps part of a dream sequence or the real deal.

    PHOTOS: Biggest style moments on Gossip Girl

    Tell Us: Should Dan and Blair get together, already?

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    6 comments

    • vinchimee  •  3 months ago
      i think blair should deal with her royal thing problem first than making another mistake of having an affair with dan while on her marriage life. and i think she should not throw any promises to chuck if she cant make it happen. series.... never been different....impossible and so unrealistic
    • Bruna  •  Montreal, Canada  •  3 months ago
      I don't know about Dan, I wish she would come back with Chuck I loved them together
    • Yani-chan  •  3 months ago
      Yes
    • skittle_bug...  •  3 months ago
      I can't believe this shows still on. It's gone SO downhill. LOved it the first year but now it's just so unrealistic, boring, and stupid.
    • Clarice  •  Calgary, Canada  •  3 months ago
      maybe they should get their info correct, because Dan & Blair have already kissed once. and it was a lot more passionate than this one looks
    • vinchimee  •  Tokyo, Japan  •  3 months ago
      after all those times chuck and blair have been through it suddenly fall on to another scenario-dan and blair thing. what kind of love was that with blair? just changing her feelings just like that. really disappointed of what's goin on in this series.