Nicole Richie Spies On 'Chuck'

Access Hollywood - June 26, 2008 12:23 AM PDT

LOS ANGELES, Calif. -- A new femme fatale is coming to "Chuck."

Nicole Richie has signed on to guest-star on an episode of the NBC series, which returns for a second season this fall, the network announced today.

[ Myanmar Celebrity PSA: Nicole Richie & Joel Madden Speak Out - Play it Now ]

The former "Simple Life" star will play the high school nemesis of Special Agent Sarah Walker (Yvonne Strahovski), who re-encounters her old bully at her 10-year reunion - with Chuck (Zachary Levi) along for the ride.

"Nicole auditioned for the part and was very funny," said Josh Schwartz, the show's executive producer. "This role is a great opportunity for her to show off her comedic skills and be diabolically evil and kick some butt. It's going to be really fun."

[ Nicole Richie - Check Out the Photos ]

Richie has shown off her acting talents in previous guest spots on shows such as "8 Simple Rules … for Dating My Teenage Daughter" and "American Dreams."

In addition, the fashion favorite is launching a jewelry line, House of Harlow 1960, named after her daughter with rocker boyfriend Joel Madden. The line will launch this fall.

[ All Access: Nicole Richie - TV - Celebrities ]

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